Nanosopic Rectifying Antenna - Seminar Report

nanosopic rectifying antenna
A nantenna (nanoantenna) is a nanosopic rectifying antenna, an experimental technology being developed to convert light to electric power. The concept is based   on the rectenna (rectifying antenna), a device used in wireless power transmission. A re-ctenna is a specialized radio antenna which is used to convert   radio waves into direct current electricity. Light is composed of electromagnetic   waves  like radio waves but of much smaller wavelength. A nantenna is a very small rectenna the size of a light wave, fabricated using nanotechnology, which acts as an "antenna" for light, converting light into electricity. It is hoped that arrays of nantennas could be an efficient means of converting sunlight into electric power, producing solar power more efficiently than conventional solar cells. 

The idea was first proposed by Robert L. Bailey in 1972. As of 2012, only a few nantenna devices have been built, demonstrating only that energy conversion is possible. It is unknown if they will ever be as cost-effective as photovoltaic cells.A nantenna is an electromagnetic collector designed to absorb specific wavelengths that are proportional to the size of the nantenna. Currently nanoantennas are designed to operate wavelengths in the range of 3–15 μm. These wavelengths correspond to photon energies of 0.08 – 0.4 eV. Based on antenna theory, a nantenna can absorb any wavelength of light efficiently provided that the size of the nantenna is optimized for that specific wavelength.
Nanotechnology builds on advances in microelectronics during the last decades of the twentieth century. The miniaturization of electrical components greatly increased the utility and portability of computers, imaging equipment, microphones, and otherelectronics.                                    
Nanotechnology is the manipulation of matter on an atomic and molecular scale. Generally, nanotechnology works with materials, devices, and other structures with at least one dimension sized from 1 to 100 nanometres. Nanotechnology may be able to create many new materials and devices with a vast range of applications, such as in medicine, electronics, biomaterials and energy production. 
On the other hand, nanotechnology raises many of the same issues as any new technology, including concerns about the toxicity and environmental impact of nanomaterials. In  original sense, nanotechnology refers to the projected ability to construct items from the bottom up, using techniques and tools being developed today to make complete, high performance products. 
One nanometer (nm) is one billionth, or 10−9, of a meter. This new phenomena make nanotechnology distinct from devices which are merely miniaturised versions of an equivalent macroscopic device; such devices are on a larger scale and come under the description of microtechnology. Areas of physics such as nanoelectronics, nanomechanics, nanophotonics and nanoionics have evolved during the last few decades to provide a basic scientific foundation of nanotechnology. Molecular nanotechnology is especially associated with the molecular assembler, a machine that can produce a desired structure or device atom-by-atom using the principles of mechanosynthesis. Nanoscale materials are sometimes used in solar cells which combats the cost of traditional Silicon solar cells. Various techniques of nanolithography such as optical lithography, X-ray lithography dip pen nanolithography, electron beam lithography or nanoimprint lithography were also developed. Lithography is a top-down fabrication technique where a bulk material is reduced in size.
Despite these fundamental advances there remain real physical constraints (e.g., microchip design limitations) to further miniaturization based upon conventional engineering principles. Nanotechnologies intend to revolutionize components and manufacturing techniques to overcome these fundamental limitations.e to nanoscale pattern. nantennas would be used to absorb light at wavelengths between 0.4 – 1.6 μm because these wavelengths have higher energy than far-infrared. 

Theory of nanoantennas
The theory behind nantennas is essentially the same for rectifying antennas. Incident light on the antenna causes electrons in the antenna to move back and forth at the same frequency as the incoming light. This is caused by the oscillating electric field of the incoming electromagnetic wave. The movement of electrons is an alternating current in the antenna circuit. To convert this into direct current, the AC must be rectified, which is typically done with some kind of diode. The resulting DC current can then be used to power an external load. The resonant frequency of antennas (frequency which results in lowest impedance and thus highest efficiency) scales linearly with the physical dimensions of the antenna according to simple microwave antenna theory. The wavelengths in the solar spectrum range from approximately 0.3-2.0 μm. 
Thus, in order for a rectifying antenna to be an efficient electromagnetic collector in the solar spectrum, it needs to be on the order of hundreds of nm in size. Because of simplifications used in typical rectifying antenna theory, there are several complications that arise when discussing nantennas. At frequencies above infrared, almost all of the current is carried near the surface of the wire which reduces the effective cross sectional area of the wire, leading to an increase in resistance. This effect is also known as the “skin effect”. From a purely device perspective, the I-V characteristics would appear to no longer be ohmic, even though Ohm’s law, in its generalized vector form, is still valid.
Another complication of scaling down is that diodes used in larger scale rectennas cannot operate at THz frequencies without large loss in power.[2] The large loss in power is a result of the junction capacitance (also known as parasitic capacitance) found in p-n junction diodes and Schottky diodes, which can only operate effectively at frequencies less than 5 THz.[3] The ideal wavelengths of 0.4–1.6 μm correspond to frequencies of approximately 190–750 THz, which is much larger than the capabilities of typical diodes. Therefore, alternative diodes need to be used for efficient power conversion. In current nantenna devices, metal-insulator-metal (MIM) tunneling diodes are used. Unlike Schottky diodes, MIM diodes are not affected by parasitic capacitances because they work on the basis of electron tunneling. Because of this, MIM diodes have been shown to operate effectively at frequencies around 150 THz.

Production of a nantenna
After the proof of concept was completed, laboratory-scale silicon wafers were fabricated using standard semiconductor integrated circuit fabrication techniques. E-beam lithography was used to fabricate the arrays of loop antenna metallic structures. The nantenna consists of three main parts: the ground plane, the optical resonance cavity, and the antenna. The antenna absorbs the electromagnetic wave, the ground plane acts to reflect the light back towards the antenna, and the optical resonance cavity bends and concentrates the light back towards the antenna via the ground plane. 

A.Lithography method
Idaho National Labs used the following steps to fabricate their nantenna arrays. A metallic ground plane was deposited on a bare silicon wafer, followed by a sputter deposited amorphous silicon layer. The depth of the deposited layer was about a quarter of a wavelength. A thin manganese film along with a gold frequency selective surface (to filter wanted frequency) was deposited to act as the antenna. Resist was applied and patterned via electron beam lithography. The gold film was selectively etched and the resist was removed.

B. Roll-to-roll manufacturing
In moving up to a greater production scale, laboratory processing steps such as the use of electron beam lithography are slow and expensive. Therefore a roll-to-roll manufacturing method was devised using a new manufacturing technique based on a master pattern. This master pattern in effect mechanically “stamps” the precision 
pattern onto an inexpensive flexible substrate and thereby creates the metallic loop elements seen in the laboratory processing steps. The master template fabricated by Idaho National Laboratories consists of approximately 10 billion antenna elements on an 8-inch round silicon wafer. Using this semi-automated process, Idaho National Labs has produced a number of 4-inch square coupons. These coupons were combined to form a broad flexible sheet of nantenna arrays.

C. Proof of principle
The proof of principle for nantennas started out with a 1 cm2 silicon substrate with the printed nantenna array filling the area. The device was tested using infrared light with a range of 3 to 15 microns. The peak emissivity is found to be centered at 6.5 microns and reaches an emissivity of 1. An emissivity of 1 means the nantenna absorbs all of the photons of a specific wavelength (in this case, 6.5 microns) that are incident upon the device. Comparing the experimental spectrum to the modeled spectrum, the experimental results are in agreement with theoretical expectations. In some areas, the nantenna had a lower emissivity than the theoretical expectations, but in other areas, namely at around 3.5 microns, the device absorbed more light than expected.
 Experimental and theoretical emissivity as a function of wavelength. The experimental spectrum was determined by heating the nantenna to 200 °C and comparing the spectral radiance to blackbody emission at 200 °C.
After a proof of concept on a stiff silicon substrate, the experiment was replicated on a flexible polymer-based substrate. The target wavelength for the flexible substrate was set to 10 microns. Initial tests show that the nantenna design can be translated to a polymer substrate, but further experiments are needed to fully optimize the characteristics.

Advantages of nantennas
One of the biggest claimed advantages of nantennas is their high theoretical efficiency. When compared to the theoretical efficiency of single junction solar cells (30%), nantennas appear to have a significant advantage. However, the two efficiencies are calculated using different assumptions. The assumptions involved in the nantenna calculation are based on the application of the Carnot efficiency of solar collectors. 
In order for there to be an efficient energy conversion, the temperature difference between the two bodies must be significant. R. L. Bailey claims that nantennas are not limited by Carnot efficiency, whereas photovoltaics are. However, he does not provide any argument for this claim. Furthermore, when the same assumptions used to obtain the 85% theoretical efficiency for nantennas are applied to single junction solar cells, the theoretical efficiency of single junction solar cells is also greater than 85%.
The most apparent advantage nantennas have over semiconductor photovoltaics is that nantenna arrays can be designed to absorb any frequency of light. The resonant frequency of a nantenna can be selected by varying its length. This is an advantage over semiconductor photovoltaics, because in order to absorb different wavelengths of light, different band gaps are needed. In order to vary the band gap, the semiconductor must be alloyed or a different semiconductor must be used altogether.

Limitations and disadvantages of nantennas
As previously stated, one of the major limitations of nantennas is the frequency at which they operate. The high frequency of light in the ideal range of wavelengths makes the use of typical Schottky diodes impractical. Although MIM diodes show promising features for use in nantennas, more advances are necessary to operate efficiently at higher frequencies.
Another disadvantage is that current nantennas are produced using electron beam (e beam -) lithography. This process 
is slow and relative ly expensive because parallel processing is not possible with e-beam lithography. Typically, e-beam lithography is used only for research purposes when extremely fine resolutions are needed for minimum feature size (typically, on the order of nanometers). However, photolithographic techniques have advanced to where it is possible to have minimum feature sizes on the order of tens of nanometers, making it possible to produce nantennas by means of photolithography.

Future research and goals
In an interview on National Public Radio's Talk of the Nation, Dr. Novack claimed that nantennas could one day be used to power cars, charge cell phones, and even cool homes. Novack claimed the last of these will work by both absorbing the infrared heat available in the room and producing electricity which could be used to further cool the room. (He did not discuss whether or not this would violate the second law of thermodynamics.)

Currently, the largest problem is not with the antenna device, but with the rectifier. As previously stated, present-day diodes are unable to efficiently rectify at frequencies which correspond to high-infrared and visible light. Therefore, a rectifier must be designed that can properly turn the absorbed light into usable energy. Researchers currently hope to create a rectifier which can convert around 50% of the antenna's absorption into energy Another focus of research will be how to properly upscale the process to mass-market production. New materials will need to be chosen and tested that will easily comply with a roll-to-roll manufacturing process.

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